There was last night…the program in questions path was there several times. I checked the (Defense + /View Defense Events) and the (Firewall / View Firewall events ) and they were both empty.
Then I executed the program in question, the the log looked as attached.
Odd, It should give you a pop-up if it tries to execute another program and record it in the log if it’s been blocked.
I think probably the best thing to do would be to search through all your rules and delete everything to do with the ggsearch and delete them - Then switch defense+\firewall into training mode and try again.
Also just make sure that IE is a trusted application also…