The IP you specified (64.233.171.83) resolves into RN-IN-F83.GOOGLE.COM. Where as asking for IPs from orkut.com returns 72.14.209.85, 72.14.209.86 & 72.14.209.87.
So, I don’t know what the relationship is between 64.233.171.83 & orkut.com, but on face value it seems the easiest way to block orkut.com is to use the hostname… like this…
Block IP IN from orkut.com to IP Zone:[LAN] where PROTO IS ANY
And if you want to blocking sending…
Block IP OUT from IP Zone:[LAN] to orkut.com where PROTO IS ANY
This way if they change servers, you’ll still be blocking them on their name.